Self-assembly of a constitutional dynamic library of Cu(II) coordination polygons and reversible sorting by crystallization.
نویسندگان
چکیده
A small coordination constitutional dynamic library (CDL) is self-assembled from Cu(2+) ions and the ortho bis-(3-acetylacetone)benzene ligand. Two coordination polygons, a rhomboid and a triangle, establish a dynamic equilibrium. Quantitative sorting of the rhomboidal polygon is reversibly obtained by crystallization. Thermodynamic and kinetic aspects ruling the CDL system have been elucidated.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 21 شماره
صفحات -
تاریخ انتشار 2013